Chemo‐enzymatic one‐pot oxidation of cyclohexane via in‐situ H2O2 production over supported AuPdPt catalysts.

The introduction of dopant concentrations Pt into supported AuPd nanoparticles, when used in conjunction with an evolved unspecific peroxygenase (UPO) from Agrocybe aegerita (PaDa-I) is demonstrated to offer high efficacy towards the one-pot selective oxidation cyclohexane KA oil (cyclohexanol and cyclohexanone), via in-situ synthesis H2O2. optimised AuPdPt/TiO2/PaDa-I system achieves significant improvements over analogous or Pd-only formulations use commercially available H2O2, this attributed increased rate H2O2 production by chemo-catalyst, which results electronic modification Pd species incorporation, upon formation trimetallic nanoalloys.